Etheroleic acid synthase
Definition:
EC Tree > 4 Lyases > 4.2 Carbon-oxygen lyases > 4.2.1 Hydro-lyases > 4.2.1.183 etheroleic acid synthase
Etheroleic acid synthase is a heme-thiolate (P450) divinyl-ether synthase found in several plants including Allium sativum (garlic) and Selaginella moellendorffii (spikemoss); it also catalyzes EC 4.2.1.121 (colneleate synthase) to a lesser extent. It converts (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate into (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoate and water. It appears in viruses and cellular organisms. Structurally it is a CYP74 divinyl-ether synthase.
Etheroleic acid synthase is a heme-thiolate (P450) divinyl-ether synthase found in several plants including Allium sativum (garlic) and Selaginella moellendorffii (spikemoss); it also catalyzes EC 4.2.1.121 (colneleate synthase) to a lesser extent. It converts (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate into (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoate and water. It appears in viruses and cellular organisms. Structurally it is a CYP74 divinyl-ether synthase.
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