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Phomopsene synthase

Definition:

EC Tree > 4 Lyases > 4.2 Carbon-oxygen lyases > 4.2.3 Acting on phosphates > 4.2.3.222 phomopsene synthase
Phomopsene synthase is a diterpene cyclase from the fungus Diaporthe amygdali; it has also been isolated from the bacteria Nocardia testacea, Nocardia rhamnosiphila and Allokutzneria albata. The A. albata enzyme also produces allokutznerene (EC 4.2.3.224) and traces of (-)-spiroviolene (EC 4.2.3.158). It cyclizes geranylgeranyl diphosphate into phomopsene and diphosphate. Structurally it is a diterpene cyclase.

References:

[1]. Lauterbach L., et al. Two bacterial diterpene synthases from Allokutzneria albata produce bonnadiene, phomopsene, and allokutznerene (2018), Angew. Chem. Int. Ed. Engl. , 57, 8280-8283.

[2]. Rinkel J., et al. Diterpene biosynthesis in actinomycetes Studies on cattleyene synthase and phomopsene synthase (2019), Angew. Chem. Int. Ed. Engl. , 58, 9230-9233.

[3]. Lauterbach L., et al. Two diterpene synthases from Chryseobacterium chryseodiene synthase and wanjudiene synthase (2020), Angew. Chem. Int. Ed. Engl. , 59, 11943-11947.

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