111004-08-1
Chemical Structure
9(S)-HpOTrE
- CAS No.: 111004-08-1
- Formula:C18H30O4
- Molecular Weight:310.43
IUPAC Name: (S,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid
InChIKey: RWKJTIHNYSIIHW-MEBVTJQTSA-N
SMILES: CC/C=C\C/C=C\C=C\[C@@H](OO)CCCCCCCC(O)=O
Biological Activity: 9(S)-HpOTrE is a monohydroperoxy polyunsaturated fatty acid produced by the action of 5-lipoxygenase (5-LO) on α-linolenic acid. It can be further metabolized to colnelenic acid by a divinyl ether synthase activity found in garlic and potato microsomal fractions. 9(S)-HpOTrE also serves as a substrate for further oxidation by both soybean and potato LOs, resulting in the formation of 9,16-dihydroperoxy acid.The suicide inactivation of LOs when 9(S)-HpOTrE is used as a substrate is thought to occur via formation of an unstable epoxide.
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9(S)-HpOTrE | 9(S)-HpOTrE is a monohydroperoxy polyunsaturated fatty acid produced by the action of 5-lipoxygenase (5-LO) on α-linolenic acid. It can be further metabolized to colnelenic acid by a divinyl ether synthase activity found in garlic and potato microsomal fractions. 9(S)-HpOTrE also serves as a substrate for further oxidation by both soybean and potato LOs, resulting in the formation of 9,16-dihydroperoxy acid.The suicide inactivation of LOs when 9(S)-HpOTrE is used as a substrate is thought to occur via formation of an unstable epoxide. | |||||||||||||||||||||
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