1226-46-6
Chemical Structure
Thiomichler's ketone
Synonym(s): 4,4'-Bis(dimethylamino)thiobenzophenone
- CAS No.: 1226-46-6
- Formula:C17H20N2S
- Molecular Weight:284.42
IUPAC Name: bis(4-(dimethylamino)phenyl)methanethione
InChIKey: KFUJUTFTRXYQMG-UHFFFAOYSA-N
SMILES: CN(C1=CC=C(C(C2=CC=C(N(C)C)C=C2)=S)C=C1)C
Biological Activity: Thiomichler's ketone (4,4'-Bis (dimethylamino) thiobenzophenone) is a heavy metal complexing agent and a colorimetric/spectrophotometric reagent. Thiomichler's ketone shows selectivity for Hg2+ at pH 3, and exhibits activity towards Pd2+ and Ag+ at pH 3.5. Thiomichler's ketone enables accurate detection of trace Pd2+ by forming an extractable Hg2+ complex via micelle-mediated cloud point extraction, or generating a red coordination complex including Pd (TMK)4. Thiomichler's ketone is applicable for the determination of trace Pd2+ in antibiotics and catalysts of automobile exhaust purifiers[1][2][3].
| Cat. No. | Product Name | Purity | Description | Pricing | |||||||||||||||||||
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Thiomichler's ketone | 81.08% | Thiomichler's ketone (4,4'-Bis (dimethylamino) thiobenzophenone) is a heavy metal complexing agent and a colorimetric/spectrophotometric reagent. Thiomichler's ketone shows selectivity for Hg2+ at pH 3, and exhibits activity towards Pd2+ and Ag+ at pH 3.5. Thiomichler's ketone enables accurate detection of trace Pd2+ by forming an extractable Hg2+ complex via micelle-mediated cloud point extraction, or generating a red coordination complex including Pd (TMK)4. Thiomichler's ketone is applicable for the determination of trace Pd2+ in antibiotics and catalysts of automobile exhaust purifiers. | ||||||||||||||||||||
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References
- [1]. Niazi A, et al. Spectrophotometric determination of mercury in water samples after cloud point extraction using nonionic surfactant Triton X-114. J Hazard Mater. 2009;165(1-3):1200-1203. [Content Brief]
- [2]. Niazi A, et al. Simultaneous spectrophotometric determination of mercury and palladium with Thio-Michler's Ketone using partial least squares regression and orthogonal signal correction. Spectrochim Acta A Mol Biomol Spectrosc. 2008;71(3):1172-1177. [Content Brief]
- [3]. TSURUBOU S, et al. Spectrophotometric Determination of Trace Amounts of Palladium in Antibiotics and Catalysts with Thio-Michler's Ketone[J]. Chemical and pharmaceutical bulletin, 1983, 31(8): 2905-2909.
