144222-34-4
144222-34-4
Chemical Structure
TsDPEN
- CAS No.: 144222-34-4
- Formula:C21H22N2O2S
- Molecular Weight:366.48
IUPAC Name: N-((1R,2R)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide
InChIKey: UOPFIWYXBIHPIP-NHCUHLMSSA-N
SMILES: N[C@@H]([C@H](NS(C1=CC=C(C)C=C1)(=O)=O)C2=CC=CC=C2)C3=CC=CC=C3
Biological Activity: TsDPEN (Compound 2) is a biochemical reagent. TsDPEN derivatives containing N,N,N imide chiral ligands can be applied to copper catalyzed asymmetric Kinugasa reactions[1][2].
| Cat. No. | Product Name | Purity | Description | Pricing | |||||||||||||||||||
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TsDPEN | 99.39% | TsDPEN (Compound 2) is a biochemical reagent. TsDPEN derivatives containing N,N,N imide chiral ligands can be applied to copper catalyzed asymmetric Kinugasa reactions. | ||||||||||||||||||||
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References
- [1]. Hayes A, et al. The importance of 1, 2-anti-disubstitution in monotosylated diamine ligands for ruthenium (II)-catalysed asymmetric transfer hydrogenation. Tetrahedron: Asymmetry, 2004, 15(13): 2079-2084.
- [2]. Xu C, et al. Development of TsDPEN based imine-containing ligands for the copper-catalysed asymmetric Kinugasa reaction. RSC Adv. 2020 May 12;10(31):18107-18114. [Content Brief]
