2143892-50-4
2143892-50-4
Chemical Structure
SulfoxFluor
- CAS No.: 2143892-50-4
- Formula:C13H11ClFNO3S2
- Molecular Weight:347.82
IUPAC Name: 4-chloro-N-tosylbenzenesulfonimidoyl fluoride
InChIKey: ZKSTYVIGFNZFRW-UHFFFAOYSA-N
SMILES: O=S(N=S(F)(C1=CC=C(C=C1)Cl)=O)(C2=CC=C(C)C=C2)=O
Biological Activity: SulfoxFluor is a fluorinated sulfoximine compound that can be used in the rapid deoxyfluorination and selective deoxyazidation reactions of various alcohols. SulfoxFluor is characterized by high reactivity, rapid reaction, simple operation, easy scale-up, and high selectivity[1][2][3][4].
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SulfoxFluor | 99.53% | SulfoxFluor is a fluorinated sulfoximine compound that can be used in the rapid deoxyfluorination and selective deoxyazidation reactions of various alcohols. SulfoxFluor is characterized by high reactivity, rapid reaction, simple operation, easy scale-up, and high selectivity. | ||||||||||||||||||||
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References
- [1]. Guo J, et al. Rapid Deoxyfluorination of Alcohols with N-Tosyl-4-chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor) at Room Temperature. Chemistry. 2019;25(30):7259-7264. [Content Brief]
- [2]. Guo J, et al. SulfoxFluor-enabled deoxyazidation of alcohols with NaN3[J]. Nat Commun. 2022 May 18;13(1):2752. [Content Brief]
- [3]. Renxiang Liu, et al. Modified and Scalable Synthesis of N-Tosyl-4-Chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor): Direct Imidation of Sulfinyl Chlorides with Chloramine-T Trihydrate[J]. American Chemical Society. 2022, 26, 2, 380-386.
- [4]. Jin P, et al. SulfoxFluor as a deoxyfluorination reagent, and beyond. Journal of Fluorine Chemistry, 2022, 261: 110029.
