819850-13-0
819850-13-0
Chemical Structure
tert-Butyl 1H-indol-4-ylcarbamate
- CAS No.: 819850-13-0
- Formula:C13H16N2O2
- Molecular Weight:232.28
IUPAC Name: tert-butyl (1H-indol-4-yl)carbamate
InChIKey: KOKLMCWYZCHYEO-UHFFFAOYSA-N
SMILES: CC(C)(OC(NC1=CC=CC2=C1C=CN2)=O)C
Biological Activity: tert-Butyl 1H-indol-4-ylcarbamate is a nucleophilic reagent. tert-Butyl 1H-indol-4-ylcarbamate induces the formation of the stable triple hydrogen-bonded complex A-TS-Re. tert-Butyl 1H-indol-4-ylcarbamate undergoes Friedel-Crafts reactions with β,γ-unsaturated α-ketiminoesters[1][2].
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tert-Butyl 1H-indol-4-ylcarbamate | tert-Butyl 1H-indol-4-ylcarbamate is a nucleophilic reagent. tert-Butyl 1H-indol-4-ylcarbamate induces the formation of the stable triple hydrogen-bonded complex A-TS-Re. tert-Butyl 1H-indol-4-ylcarbamate undergoes Friedel-Crafts reactions with β,γ-unsaturated α-ketiminoesters. | |||||||||||||||||||||
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References
- [1]. Ding Y Y, et al. Chiral Phosphoric Acid Catalyzed Enantioselective Friedel‐Crafts Reaction of N‐Protected 4‐Aminoindoles with β, γ‐Unsaturated α‐Ketimino Esters[J]. Advanced Synthesis & Catalysis, 2018, 360(4): 664-669.
- [2]. Ahmad T, et al. Recent Advances in the Catalytic Asymmetric Friedel-Crafts Reactions of Indoles. ACS Omega. 2022;7(40):35446-35485. Published 2022 Oct 3. [Content Brief]
